Product ID:624011 CYCLOHEXYLAMINE
MSDS Date:02/22/1995
FSC:6810
NIIN:00-805-9798
MSDS Number: CCHVL

VAN WATERS AND ROGERS INC

6100 CARILLON POINT
KIRKLAND, WA 98033
US

Emergency Phone: 206-889-3400

Info Phone: 206-889-3400

Cage: 0STM5

VOPAK USA INC

KIRKLAND, WA 98033-7357 US

Telephone: 425-889-3400/425-889-3617

Cage: 0STM5

CYCLOHEXYLAMINE (SARA 302)

CAS: 108-91-8

RTECS: GX0700000

Fraction By Weight: 99%

OSHA PEL 10 PPM

ACGIH TLV: 10 PPM; 9596

CYCLOHEXANOL

CAS: 108-93-0

RTECS: GV7875000

Fraction By Weight: 0.1%

OSHA PEL S, 50 PPM

ACGIH TLV: S, 50 PPM; 9596

LD50 LC50 Mixture:ORAL LD50 (RATS): 156-710MG/KG.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:SKIN:LIQ CAN CAUSE SEVERE SKIN
EFFECTS, INCLUDING BURNS & SKIN CORR.EYE:CONTACT W/LIQ CAN BE CORR
TO EYES,RESULTING IN IRREVERSIBLE DMG.CONTACT W/VAP CAN CAUSE
IRRIT.CONTACT W/EXCESSIVE VAP MAY CAUSE TRANSIENT VISUAL
DISTRUBANCES CHARACTERIZED BYMILDLY BLURRED VISION & BLUE-GREY
DISCOLORIZATION OF SIGHT DUE TO (SUPPLE)
Explanation of Carcinogenicity:PER MSDS:NOT CARCINOGENIC IN CHRONIC
FEEDING STUDIES W/RATS/MICE.
Effects of Overexposure:SEVERE SKIN EFFECTS-BURNS,CORR.CORR TO EYES
IRREVERSIBLE DMG,IRRIT FROM VAP,TRANSIENT VISUAL DISTURB
CHARACTERIZED BY MILDLY BLURRED VISION,BLUE-GREY DISCOLORIZATION OF
SIGHT(BLUE HAZE/HALO VISION).MI LD CORNEAL IRRIT,EDEMA.COUGH,CHEST
PAIN,BREATH DIFFI,LOSS OF MUSCLE
COORDINATION,HEAD,VOMIT,DIARR,CARDIOVASCULAR EFFECTS
Medical Cond Aggravated by Exposure:RESPIRATORY DISEASES & SKIN
DISORDERS.MAY PROVOKE ASTHMATIC RESPONSE IN PERSONS W/ASTHMA WHO
ARE PARTICULARLY SENSITIVE TO RESP IRRITANTS.

First Aid:SKIN:REMOVE CONTAMIN CLOTH.WASH W/LG AMTS OF WATER.ASAP WASH
W/VINEGAR FORMIN OF 1MIN TO NEUTRALIZE/SOLUBILITY RESIDUE AMINE
FOLLOWED BY WATER RINSE.REPEAT VINEGAR WATER PROCESS IF STICKINESS
PERSISTS .SIGNIFICANT IRRIT SIGNS SEE DR.EYE:FLUSH W/WATER FOR
@LEAST 15MINS.SEE DR IMMED.INHAL:REMVOE FROM CONTAMIN AREA.BREATH
STOP GIVE ART RESP THEN OXY IF NEEDED.SEE DR IMMED.INGEST:DRINK LG
QUANT OF(SUP)

Flash Point Method:SCC
Flash Point:83.0F,28.3C
Autoignition Temp:Autoignition Temp Text:560F
Lower Limits:0.66
Upper Limits:>8.2
Extinguishing Media:USE CARBON DIOXIDE,DRY CHEM FOR SMALL
FIRES;ALCOHOL-TYPE AQUEOUS FILM-FORMING FOAM,WATERSPRAY FOR LG
FIRES.
Fire Fighting Procedures:WEAR COMPLETE PPE INCLUDE SCBA W/FULL FCPIECE
OPERATE IN PRESS DEMAND/OTHER +PRESS MODE.H2OSPRAY REDUCE FLAME
INTENSITY/DIL SPILL TO NONFLAMM/COOL FIRE-EXPO CNT
Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER.

Spill Release Procedures:REMOVE IGN SOURCES.AVOID EYE/SKIN
CONTACT.PLACE LEAK CNTNR IN WELL VENTI AREA W/SPILL
CONTAINMENT.FIRE POT BLANKET W/ALCOHL-TYP AQU FILM-FORM
FOAM/H2OSPRAY TO DISPERSE VAP.CONTAIN SPILL.CLEANUP:ABSORB ENT
MATL,VAC TRUCK,ETC.PREVENT RUNOFF (OTHER PREC)
Neutralizing Agent:SULFAMIC ACID OR SODIUM BISULFATE.

Handling and Storage Precautions:STORE IN COOL WELL VENTI AREA AWAY
FROM SPARKS/FLAME.KEEP CNTNR CLSD WHEN NOT IN USE.OPEN
SLOWLY-EXCESS PRESSURE RELEASES.PROPER GROUND PROCEDURES.
Other Precautions:KEEP AWAY FROM ACIDS/OXIDIZERS.USE SPARK-RESIST
TOOLS.SPILL:INTO STORM SEWERS/DITCHE/NAT WATERWAYS.NEUTRALIZE
W/SULFAMIC ACID OR SODIUM BISULFATE.CALL NAT RESP CNTNR
800-424-8802 IF SPILL =/>RQ OF 1LG /DAY.

Respiratory Protection:BASED ON CONTAMIN LEVEL & WORKING LIMITS OF RESP
USE RESP APPROVED BY NIOSH/MSHA:AIR-PURIFY RESP W/FULL FCPC &
AMMONIA/METHYLAMINES CARTRIDGES;SUPPLIED AIR RESP;+PRESSURE SCBA
W/FULL FCPC.
Ventilation:GENERAL/DILUT VENTI FREQUENTLY INSUFFICINET AS SOLE MEANS
CNTRL EXPO.LOCAL VENTI USUALLY PREFERRED.
Protective Gloves:NEOPRENE,RUBBER GLOVES.
Eye Protection:CHEM SAFETY GOGGLES.
Other Protective Equipment:SAFETY SHOWER/EYE BATH READILY
AVIALBLE.DON'T WEAR CONTACT LENSES.
Work Hygienic Practices:AVOID BREATH VAP/EYE/SKIN/CLOTH
CONTACT.DECONTAM SOILD CLOTH WELL;DISCARD CONTAM LEATHER.WASH WELL
W/SOAP/WATER AFT HNDL
Supplemental Safety and Health
COMBUST PROD:PRODUCTS + CO,CYANIDES,NITRILES. HEALTH HAZ:MILD CORNEAL
IRRIT/EDEMA(DISSAPPEAR SEVEREAL HRS).INHAL:IRRIT RESP SYS,.PULM
EDEMA.INGEST:IRRIT/BURN MOUTH/THROAT/ESOPHAGUS/STOMACH.NAU,VOMIT,D
IARR,CARDIOVASCULAR EFECTS. 1STAID:H2O.DON'T INDUCE VOMIT.SEE DR
IMMED.DR:TREAT AS ALKALINE SUBST(SIMILAR TO AMMONIA).

HCC:F7
Boiling Pt:B.P. Text:274F,135C
Melt/Freeze Pt:M.P/F.P Text:0F,-18C
Decomp Temp:Decomp Text:NP
Vapor Pres:11 @20C
Vapor Density:3.42
Spec Gravity:0.867
pH:NP
Viscosity:NP
Evaporation Rate & Reference:NO INFORMATION.
Solubility in Water:COMPLETE.
Appearance and Odor:CLEAR LIQUID, AMMONIA-LIKE ODOR.
Percent Volatiles by Volume:NP
Corrosion Rate:NP

Stability Indicator/Materials to Avoid:YES
MAY REACT VIGOROUSLY W/OXIDIZING AGENTS.TYPICAL OXIDIZING AGENTS
INCLUDE PERCHLORATES,NITRATES,PERMANGANATES.
Stability Condition to Avoid:HEAT, SPARKS, FLAMES.
Hazardous Decomposition Products:IN PRESENCE OF SUFFI OXY:OXIDES OF
NITROGEN,CO2.NITROGEN OXIDES RX W/WATER PRODUCE HNO3.OXY
STARVED:NUMEROUS TOXIC(SUPP)

Waste Disposal Methods:ALL NOTIFICATION/CLEANUP/DISPO SHOULD BE CARRIED
OUT IAW FED/STATE/LOC REGS.PREFERRED METHODS OF WASTE
DISPO:INCINERATION OR BIOLOGICAL TREATMENT IN FED/STATE APPROVED
FACILITY.FINAL RESPONSIBILITY FO R HDNLG/DISPO IS W/ONER OF WASTE.

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of Defense. The United States of America in no manner whatsoever,
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disclaims all liability for its use. Any person utilizing this
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assume responsibility for the suitability of this information to their
particular situation.